Abstract
Airbags are a landmark in automotive passive safety; their deployment relies on tightly controlled chemical reactions that generate large volumes of inert gas within milliseconds. Sodium azide (NaN₃) historically dominated as gas generant; however, its toxicity and thermal instability fostered safer alternatives such as nitroguanidine, guanidine nitrate, and hybrid formulations with ammonium nitrate or compressed gas inflators. This article offers a critical review of the chemical evolution of airbag inflators, examines the thermodynamics and kinetics of core reactions, discusses toxicological and environmental risks, and evaluates sustainability driven trends—green chemistry, modular design and end of life recycling—that will shape the industry’s future. We conclude that, although recent advances substantially reduce exposure to hazardous by products and improve energetic efficiency, challenges remain in post deployment waste management and global regulatory harmonisation.
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References
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